Is Sulfuric Acid (H₂SO₄) a Strong or Weak Acid?

Is Sulfuric Acid (H₂SO₄) a strong or weak acid?

H2SO4 is a strong diprotic acid. The first dissociation (pKa = -3) is complete. The second dissociation (HSO4- -> SO4^2-, pKa = 1.99) is weak. The sulfate ion is stabilized by resonance across four oxygen atoms.

FormulaH₂SO₄
NameSulfuric Acid
CategoryStrong acid
pKa-3
ConjugateHydrogen sulfate ion (HSO₄⁻)
Key ConceptPolyprotic, first dissociation

Definition

Sulfuric acid is a strong diprotic acid - it can donate two protons. The first dissociation is complete (strong), but the second is weak.

Acidic Proton / Active Site

Both -OH hydrogens are acidic. The first proton is easily donated (pKa -3, strong acid). After losing the first H+, the remaining HSO4- is a weak acid for the second proton.

Conjugate Pair

First: H2SO4 -> HSO4- + H+. Second: HSO4- -> SO4^2- + H+. The sulfate dianion (SO4^2-) has resonance stabilization across all four oxygens.

Strength Classification

pKa1 = -3 (strong, complete dissociation). pKa2 = 1.99 (weak). Sulfuric acid is the most widely used industrial chemical and a common strong acid in chemistry courses.

See acidic protons, conjugate base overlays, and pKa labels on interactive 3D molecules.

Explore Sulfuric Acid's Acid-Base Properties in 3D

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