Is Hydroiodic Acid (HI) a Strong or Weak Acid?

Is Hydroiodic Acid (HI) a strong or weak acid?

HI is the strongest of the hydrohalic acids. Iodine is the largest halogen, forming the weakest H-X bond. The iodide ion is very stable because the negative charge is spread over a large atom.

FormulaHI
NameHydroiodic Acid
CategoryStrong acid
pKa-10
ConjugateIodide ion (I⁻)
Key ConceptStrongest hydrohalic acid

Definition

HI is a strong Bronsted-Lowry acid. It completely donates its proton to water. It is the strongest of the common hydrohalic acids.

Acidic Proton / Active Site

The hydrogen bonded to iodine is the acidic proton. The H-I bond (297 kJ/mol) is the weakest of the H-X bonds.

Conjugate Pair

HI donates H+ to form I- (iodide). Iodide is an exceptionally weak conjugate base due to its large size and high polarizability.

Strength Classification

HI has pKa = -10, making it the strongest hydrohalic acid. The trend HF < HCl < HBr < HI shows that bond strength (not electronegativity) controls acidity down a group.

See acidic protons, conjugate base overlays, and pKa labels on interactive 3D molecules.

Explore Hydroiodic Acid's Acid-Base Properties in 3D

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