Is Sodium Chloride (NaCl) Ionic or Covalent?

Is Sodium Chloride (NaCl) ionic or covalent?

NaCl is the classic ionic compound. Sodium (EN 0.93) transfers its valence electron to chlorine (EN 3.16), creating Na+ and Cl- ions held together by electrostatic attraction.

FormulaNaCl
NameSodium Chloride
Bond TypeIonic
EN ValuesNa: 0.93, Cl: 3.16
EN Difference2.23
Electron BehaviorTransfer
Melting Point801 C (high)
ConductivityConducts when dissolved or molten
SolubilitySoluble in water
Key ConceptClassic ionic bond with large EN difference

Overview

Sodium chloride (table salt) is the textbook example of an ionic compound. A metal (Na) bonds with a nonmetal (Cl) through electron transfer.

Electronegativity Analysis

Na has an EN of 0.93 and Cl has an EN of 3.16. The difference of 2.23 is well above the 1.7 threshold for ionic character.

Electron Behavior

Sodium completely transfers its one valence electron to chlorine. This creates Na+ and Cl- ions. The bond is an electrostatic attraction between these ions.

Physical Properties

Ionic compounds like NaCl have high melting points (801 C), conduct electricity when dissolved or molten (free ions carry charge), and are typically soluble in water.

See electronegativity values, partial charges, and bond character on interactive 3D molecules.

Visualize Sodium Chloride's Bonding in 3D

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