Electron Configuration of Arsenic (As)

What is the electron configuration of Arsenic?

The electron configuration of Arsenic (As, Z=33) is 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p³. In noble gas shorthand: [Ar] 3d¹⁰ 4s² 4p³. It has 3 unpaired electron(s) and is a p-block element.

SymbolAs
Atomic Number33
Full Electron Configuration1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p³
Noble Gas Shorthand[Ar] 3d¹⁰ 4s² 4p³
Blockp
Period4
Group15
Unpaired Electrons3
Exception?No

Orbital Filling Order

Following the aufbau principle, the 33 electrons in Arsenic fill orbitals in order of increasing energy: 1s (2 electrons), then 2s (2 electrons), then 2p (6 electrons), then 3s (2 electrons), then 3p (6 electrons), then 3d (10 electrons), then 4s (2 electrons), then 4p (3 electrons).

Each orbital is filled according to the Pauli exclusion principle (at most 2 electrons per orbital) and Hund's rule (electrons occupy degenerate orbitals singly before pairing).

Noble Gas Shorthand

The inner electrons of Arsenic match the configuration of Ar. This allows us to abbreviate the configuration as [Ar] 3d¹⁰ 4s² 4p³, where [Ar] represents the filled core and the remaining entries show the valence electrons.

Valence Electrons

The valence shell of Arsenic contains 10 electrons in the 3d subshell and 2 electrons in the 4s subshell and 3 electrons in the 4p subshell. These outermost electrons determine Arsenic's chemical reactivity, bonding behavior, and position in the periodic table as a p-block element in period 4.

Visualize orbital filling with 3D orbital shapes, aufbau principle, and noble gas shorthand for 36 elements.

Explore Arsenic in the Electron Configuration Explorer

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