Lewis Structure of CO (Carbon Monoxide)
What is the Lewis structure of CO?
CO has 10 valence electrons, 3 bonding electron pairs, and 2 lone pairs. CO has 10 valence electrons. Six are shared in a C-O triple bond, and each atom has one lone pair. Unusually, carbon has a formal charge of -1 and oxygen has +1, making CO a strong ligand in coordination chemistry.
| Formula | CO |
| Name | Carbon Monoxide |
| Total Valence Electrons | 10 |
| Lone Pairs | 2 |
| Has Resonance | No |
| Concept | Multiple Bonds |
| Difficulty | Intermediate |
Step 1: Count Valence Electrons
C has 4, O has 6: 4 + 6 = 10 total valence electrons.
Step 2: Draw the Skeleton
Start with a single bond (2 electrons). 8 remain.
Step 3: Distribute Lone Pairs
After forming the triple bond, each atom has 1 lone pair (2 electrons).
Step 4: Form Multiple Bonds
Convert lone pairs into bonding pairs until both atoms have octets: single to triple bond (C≡O). Each atom: 6 bonding + 2 lone pair = 8 electrons.
Step 5: Check Formal Charges
- C: FC = 4 - 2 - ½(6) = -1
- O: FC = 6 - 2 - ½(6) = +1
- The negative charge on C (more electropositive atom) is counterintuitive but correct.
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