Lewis Structure of NO₂⁻ (Nitrite Ion)

What is the Lewis structure of NO₂⁻?

NO₂⁻ has 18 valence electrons, 3 bonding electron pairs, and 6 lone pairs. NO₂⁻ has 18 valence electrons (17 + 1 for the charge). Two resonance structures exist where the double bond alternates between the two N–O bonds. Brackets with a -1 superscript indicate the overall charge.

O-1NO
Lewis structure of NO₂⁻ (Nitrite Ion)
FormulaNO₂⁻
NameNitrite Ion
Total Valence Electrons18
Lone Pairs6
Has ResonanceYes
Resonance Structures2
ConceptPolyatomic Ion
DifficultyAdvanced

Step 1: Count Valence Electrons

N has 5, each O has 6, plus 1 for the negative charge: 5 + 6 + 6 + 1 = 18.

Step 2: Draw the Skeleton

Nitrogen is central, bonded to two oxygens. Two single bonds use 4 electrons; 14 remain.

Step 3: Distribute Lone Pairs

Distribute: 3 lone pairs on each O (12 e⁻) + 1 on N (2 e⁻) = 14. N only has 6 e⁻ — needs 8.

Step 4: Form Multiple Bonds

Convert 1 lone pair from an O to a π bond: N=O double bond. N now has 8 electrons.

Step 5: Check Formal Charges

Resonance Structures

NO₂⁻ has 2 resonance structures. The actual electronic structure is a hybrid of all resonance contributors.

ONO-1
Resonance structure 2

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