Lewis Structure of SO₄²⁻ (Sulfate)
What is the Lewis structure of SO₄²⁻?
SO₄²⁻ has 32 valence electrons, 4 bonding electron pairs, and 12 lone pairs. SO₄²⁻ has 32 valence electrons. Eight are in four S-O single bonds, and 24 form 3 lone pairs on each oxygen. In the octet-following structure, S has FC = +2 and each O has FC = -1. Some textbooks use double bonds (expanded octet) to reduce formal charges.
| Formula | SO₄²⁻ |
| Name | Sulfate |
| Total Valence Electrons | 32 |
| Lone Pairs | 12 |
| Has Resonance | No |
| Concept | Polyatomic Ion |
| Difficulty | Advanced |
Step 1: Count Valence Electrons
S has 6, each O has 6, plus 2 for the charge: 6 + 4(6) + 2 = 32.
Step 2: Draw the Skeleton
Sulfur is central, bonded to four oxygens. Four single bonds use 8 electrons; 24 remain.
Step 3: Distribute Lone Pairs
Each O gets 3 lone pairs (6 electrons x 4 = 24). All 24 remaining electrons used. S has a full octet from 4 bonds.
Step 4: Form Multiple Bonds
The octet-following structure uses all single bonds. Expanded octet versions with S=O double bonds exist but are debated in introductory courses.
Step 5: Check Formal Charges
- S: FC = 6 - 0 - ½(8) = +2
- O: FC = 6 - 6 - ½(2) = -1 (each)
- Net: +2 + 4(-1) = -2, matching the ion charge.
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