Lewis Structure of XeF₂ (Xenon Difluoride)
What is the Lewis structure of XeF₂?
XeF₂ has 22 valence electrons, 2 bonding electron pairs, and 9 lone pairs. XeF₂ has 22 valence electrons. Four are in two Xe-F bonds, 6 form 3 lone pairs on xenon, and 12 form 3 lone pairs on each fluorine. Xenon has 10 electrons around it (expanded octet). The 3 lone pairs occupy equatorial positions, giving a linear molecular geometry.
| Formula | XeF₂ |
| Name | Xenon Difluoride |
| Total Valence Electrons | 22 |
| Lone Pairs | 9 |
| Has Resonance | No |
| Concept | Expanded Octet |
| Difficulty | Advanced |
Step 1: Count Valence Electrons
Xe (Group 8A) has 8, each F has 7: 8 + 2(7) = 22 total.
Step 2: Draw the Skeleton
Xenon forms 2 single bonds to fluorine, using 4 electrons; 18 remain.
Step 3: Distribute Lone Pairs
Each F gets 3 lone pairs (12 electrons). 6 electrons remain as 3 lone pairs on Xe. Total on Xe: 10 electrons (expanded octet).
Step 4: Form Multiple Bonds
No multiple bonds. Xe has 2 bonds + 3 lone pairs = 10 electrons. Noble gases can form compounds when they use d orbitals.
Step 5: Check Formal Charges
- Xe: FC = 8 - 6 - ½(4) = 0
- F: FC = 7 - 6 - ½(2) = 0
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