IUPAC Name of C₅H₁₂O | 2-methylbutan-2-ol

What is the IUPAC name of C₅H₁₂O?

The IUPAC name of C₅H₁₂O is 2-methylbutan-2-ol. It is a alcohol with a 4-carbon parent chain (butan-2-ol) with a methyl at position 2 substituent.

FormulaC₅H₁₂O
IUPAC Name2-methylbutan-2-ol
Compound ClassAlcohol
Parent Chainbutan-2-ol (4 carbons)
Substituentsmethyl at C2
DifficultyAdvanced

Step 1: Identify the Parent Chain

The longest continuous carbon chain in C₅H₁₂O contains 4 carbon atoms, giving the parent name butan-2-ol. The parent chain must include the carbon bearing the hydroxyl (-OH) group.

Step 2: Number and Name Substituents

Number the parent chain so that substituents receive the lowest possible locants. 2-methylbutan-2-ol has one substituent:

Step 3: Assemble the IUPAC Name

Combine the substituent locants and names (in alphabetical order) as prefixes to the parent chain name. If two or more identical substituents are present, use the multiplying prefixes di-, tri-, tetra-, etc. The complete IUPAC name is 2-methylbutan-2-ol.

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