Is Benzene (C₆H₆) Polar or Nonpolar?

Is Benzene (C₆H₆) polar or nonpolar?

Benzene has six slightly polar C–H bonds (ΔEN = 0.35) arranged in a perfect hexagon. The D₆ₕ symmetry means every dipole is canceled by the one directly across the ring.

FormulaC₆H₆
PolarityNonpolar
Molecular GeometryPlanar Hexagonal
C–H BondΔEN = 0.35 (weakly polar)
Net DipoleNo - dipoles cancel

Bond Dipoles

Each C–H bond has ΔEN = 0.35. The C–C bonds within the ring are nonpolar. Six C–H dipoles point radially outward from the hexagonal ring.

Molecular Shape & Dipole Cancellation

Benzene is a perfect regular hexagon (D₆ₕ symmetry). Each C–H bond dipole has an identical dipole pointing in the exact opposite direction across the ring.

Net Dipole Moment

The perfect hexagonal symmetry cancels all dipoles. Benzene is nonpolar - it doesn't mix with water but is an excellent solvent for other nonpolar compounds.

See bond dipoles, partial charges, and net dipole moments on interactive 3D molecules.

Visualize Benzene's Polarity in 3D

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