Is Hydrogen Chloride (HCl) Polar or Nonpolar?

Is Hydrogen Chloride (HCl) polar or nonpolar?

HCl has a single polar bond (ΔEN = 0.96). As a diatomic molecule, the bond dipole IS the molecular dipole - there is nothing to cancel it.

FormulaHCl
PolarityPolar
Molecular GeometryLinear
H–Cl BondΔEN = 0.96 (polar)
Net DipoleYes

Bond Dipoles

The H–Cl bond has an electronegativity difference of 0.96 (Cl = 3.16, H = 2.20). Chlorine pulls electron density toward itself, creating a δ- on Cl and δ+ on H.

Molecular Shape & Dipole Cancellation

HCl is a diatomic molecule - linear by definition. With only one bond, there is no possibility of cancellation.

Net Dipole Moment

The molecular dipole equals the bond dipole, pointing from H toward Cl. HCl is polar and dissolves in water to form hydrochloric acid.

See bond dipoles, partial charges, and net dipole moments on interactive 3D molecules.

Visualize Hydrogen Chloride's Polarity in 3D

Related Topics