Is Ammonia (NH3) Ionic or Covalent?

Is Ammonia (NH3) ionic or covalent?

Ammonia has moderately polar N-H bonds. Nitrogen (EN 3.04) pulls shared electrons slightly more than hydrogen (EN 2.20), and the lone pair on N makes the molecule a good base.

FormulaNH3
NameAmmonia
Bond TypePolar Covalent
EN ValuesN: 3.04, H: 2.2
EN Difference0.84
Electron BehaviorUnequal sharing
Melting Point-78 C (low)
ConductivityWeak conductor in solution (acts as base)
SolubilityVery soluble in water
Key ConceptModerately polar N-H bonds with lone pair

Overview

Ammonia has three N-H bonds arranged in a trigonal pyramidal shape. The nitrogen also carries a lone pair of electrons.

Electronegativity Analysis

Nitrogen has an EN of 3.04, hydrogen has 2.20. The difference of 0.84 puts N-H bonds squarely in the polar covalent range.

Electron Behavior

Electrons are shared unequally, pulled slightly toward nitrogen. This gives nitrogen a partial negative charge and each hydrogen a partial positive charge.

Physical Properties

Ammonia is very soluble in water due to its polarity and ability to form hydrogen bonds. It acts as a weak base in water (NH3 + H2O -> NH4+ + OH-).

See electronegativity values, partial charges, and bond character on interactive 3D molecules.

Visualize Ammonia's Bonding in 3D

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