Is Hydrogen Chloride (HCl) Ionic or Covalent?

Is Hydrogen Chloride (HCl) ionic or covalent?

HCl has a polar covalent bond. Chlorine pulls electrons closer, creating partial charges. In water, it completely dissociates into H+ and Cl-.

FormulaHCl
NameHydrogen Chloride
Bond TypePolar Covalent
EN ValuesH: 2.2, Cl: 3.16
EN Difference0.96
Electron BehaviorUnequal sharing
Melting Point-114 C (low)
ConductivityConducts in aqueous solution (strong acid)
SolubilityVery soluble in water
Key ConceptPolar covalent bond that fully dissociates in water

Overview

Hydrogen chloride is a diatomic molecule with a polar covalent bond. It dissolves in water to form hydrochloric acid.

Electronegativity Analysis

H has EN 2.20, Cl has 3.16. The difference of 0.96 is clearly polar covalent.

Electron Behavior

Electrons are shared unequally, pulled toward chlorine. Despite being covalent in the gas phase, HCl fully ionizes in water.

Physical Properties

HCl is a gas at room temperature. Dissolved in water, it is a strong acid that conducts electricity well.

See electronegativity values, partial charges, and bond character on interactive 3D molecules.

Visualize Hydrogen Chloride's Bonding in 3D

Related Topics